Try liquid latex and a silicone shiner...
I just would not try to paint any places that touch fabric...I painted a piece of furniture with high gloss latex paint. I want it shinier, what can I do?
Depending on how serious you are and what your budget is, there are many options available to make your furniture look professionally smooth and shiny. I would work really hard at sanding and smoothing. Rent or buy a power sander and work from rough sandpaper to super fine. Then use a power buffer, prime, and paint with glossy paint. There are many various types of polyurethane overcoats that won't look yellow. This site may give you some other ideas:
http://home.howstuffworks.com/guide-to-furniture-finishes-ga.htm
You could try spray painting it with clear acrylic use several coats and sand with some ultra fine automotive sandpaper between coats.
Furniture polish.
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